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  • Open Access

    ARTICLE

    Optimizing Hybrid Fibre-Reinforced Polymer Bars Design: A Machine Learning Approach

    Aneel Manan1, Pu Zhang1,*, Shoaib Ahmad2, Jawad Ahmad2

    Journal of Polymer Materials, Vol.41, No.1, pp. 15-44, 2024, DOI:10.32604/jpm.2024.053859

    Abstract Fiber-reinforced polymer (FRP) bars are gaining popularity as an alternative to steel reinforcement due to their advantages such as corrosion resistance and high strength-to-weight ratio. However, FRP has a lower modulus of elasticity compared to steel. Therefore, special attention is required in structural design to address deflection related issues and ensure ductile failure. This research explores the use of machine learning algorithms such as gene expression programming (GEP) to develop a simple and effective equation for predicting the elastic modulus of hybrid fiber-reinforced polymer (HFPR) bars. A comprehensive database of 125 experimental results of HFPR… More >

  • Open Access

    ARTICLE

    Rheological Investigation on a Polypropylene/Low Density Polyethylene Blending Melt

    Huayong Liao1,2,3,*, Jing Gao1,2,3, Chunlin Liu1,2,3, Guoliang Tao1,2,3

    Journal of Polymer Materials, Vol.41, No.1, pp. 45-54, 2024, DOI:10.32604/jpm.2024.053021

    Abstract Polymer blending with co-continuous morphology has garnered the interest of many researchers, but corresponding rheological models are rarely presented. In this study, the dynamic rheological behavior of a blend of polypropylene (PP) and low-density polyethylene (LDPE) in the ratio of 50/50 wt% is investigated, and a rheological model suggested by Yu et al. is used to fit the dynamic modulus. The rheological measurement shows that at low frequency, pure PP has higher complex viscosity and dynamic modulus than LDPE. SEM images reveal that the morphology among the 40/60 and 60/40 blends is non-dispersive. The fitting… More >

  • Open Access

    ARTICLE

    Investigation of the Damping Abilities of Sheep Wool Reinforced Expanded Polystyrene Core Layer Composites at Different Energies

    İbrahim Yavuz1,*, Ercan Şimşir1, Kenan Budak2

    Journal of Polymer Materials, Vol.41, No.1, pp. 1-14, 2024, DOI:10.32604/jpm.2024.052279

    Abstract In this study, natural fiber reinforced polymer foam core layered composites were produced for the automotive industry. Sheep wool was used as natural fiber. Polymer foam with a single layer XPS foam structure was used as the core material. XPS foams and fibers are bonded to the upper and lower sides of the foams with the help of resin. Samples were produced with one and two layers on both sides, with a total of two and four layers. Production was carried out using the vacuum bagging method using the manual laying method. After the production More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Epoxy methacrylate of (2E, 6E)-Bis(4-hydroxybenzylidene)-4- methylcyclohexanone

    JALPA V. CHOPDA, DHARMESH B. SANKHAVARA, JIGNESH P. PATEL, P. H. PARSANIA*

    Journal of Polymer Materials, Vol.36, No.4, pp. 391-399, 2019, DOI:10.32381/JPM.2019.36.04.8

    Abstract The epoxymethcrylate resin (EMBHBCMA) of (2E, 6E)-bis(4-hydroxybenzylidene)-4- methylcyclohexanone(EMBHBC) was synthesized by condensing EMBHBC and methacrylic acid (1:2 mole ratio) by using 1,4-dioxane as a solvent and triethylamine as a catalyst at reflux temperature for 1-5 h to get acid value < 10. The structure of EMBHBCMA was supported by UV-Vis, FTIR, 1 HNMR and 13CNMR spectroscopic techniques. Molecular weights and molecular weight distribution of EMBHBCMA were determined by gel permeation chromatography. EMBHBCMA is thermally stable up to about 300°C and followed two step degradation reactions. Kinetic parameters such as n, Ea, A and ΔS* were determined More >

  • Open Access

    ARTICLE

    Study on Flame-retardant Mechanism of Epoxy Resin containing Polyvinylphenylsilsesquioxane

    JIANGBO WANG*

    Journal of Polymer Materials, Vol.36, No.4, pp. 381-389, 2019, DOI:10.32381/JPM.2019.36.04.7

    Abstract In this study, a novel flame retardant polyvinylphenylsilsesquioxane (PVP) was added into epoxy resin (EP) to prepare EP/PVP (FREP) composites. The results of cone calorimeter measurement showed that in comparison with virgin EP, the peak heat release rate (PHRR) and total heat release (THR) of FREP were reduced by 27.3% and 10.4%, respectively. Moreover, the thermal degradation behavior of FREP was studied by the Kissinger and Ozawa-Flynn-Wall methods. The results suggested that the addition of PVP greatly enhanced the thermal stability of EP in the final stage, which could be attributed to that the branched More >

  • Open Access

    ARTICLE

    Synthesis and Physico-Chemical Analysis of Epoxy Methacrylate of (2E, 6E)-2,6-Bis(4- hydroxybenzylidene)cyclohexanone

    DHARMESH B. SANKHAVARA, JALPA V. CHOPDA, JIGNESH P. PATEL, PARSOTAM H. PARSANIA*

    Journal of Polymer Materials, Vol.36, No.4, pp. 371-379, 2019, DOI:10.32381/JPM.2019.36.04.6

    Abstract The epoxy methacrylate of (2E,6E)-2, 6-bis(4-hydroxybenzylidene)cyclohexanone (EBHBCMA) was synthesized by condensing 0.02 equi. EBHBC, 0.04 equi. methacrylic acid, 50 mL THF as a solvent and 0.2 mL triethylamine as a catalyst at reflux temperature for 1-5 h to get acid value < 10. EBHBCMA showed good solubility in common solvents. The structure of EBHBCMA was supported by UV-Vis., FTIR, 1 H NMR, and 13C NMR spectroscopic techniques. DSC thermogram of EBHBCMA exhibited two endothermic peaks (86.4 and 117.1 °C) and one exothermic peak (142.6°C) due to moisture release, melting and curing of the resin, respectively. More >

  • Open Access

    ARTICLE

    An Experimental Study and Analysis of Different Dielectrics in Electrical Discharge Machining of Al 6063 Alloy

    B. MOULIPRASANTHA, P. HARIHARANB

    Journal of Polymer Materials, Vol.36, No.4, pp. 351-369, 2019, DOI:10.32381/JPM.2019.36.04.5

    Abstract Electrical discharge machining is a non-traditional machining processes in which it is based upon thermal and electrical energy source as an interval energy pulse discharge in-between the work piece and tool electrode so as to remove the material. A systematical investigation of melting and vaporising of aluminium to find the output responses such as Material removal rate (MRR), Electrode wear rate (Ra), and Surface finish (EWR) in EDM using two different dielectrics was conducted as experimental work. The working fluids are Polyethylene glycol (PEG 600) and kerosene. It is the hour of need to get the More >

  • Open Access

    ARTICLE

    Effect of Synthesis Parameters on Phosphoric Acid Doped Polybenzimidazole Membranes: A Parametric Evaluation from Microstructural Level to Fuel Cell Performance

    ÇAĞLA GÜL GÜLDİKEN, LEVENT AKYALÇIN, HASAN FERDİ GERÇEL*

    Journal of Polymer Materials, Vol.36, No.4, pp. 337-349, 2019, DOI:10.32381/JPM.2019.36.04.4

    Abstract In the present study, polybenzimidazole (PBI) polymer which has a great importance in polymer electrolyte membrane (PEM) research was synthesized via the solution polycondensation method, under various synthesis conditions to put forward the effect of the synthesis parameters on the properties of the synthesized polymer and consequently to the quality of the prepared polymer electrolyte membrane. The synthesized polymers were characterized in terms of their chemical structure, thermal degradation behaviour, and molecular weight by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (1 H NMR), thermogravimetric analysis (TGA). The Mechanical properties, acid-doping level capacity, proton More >

  • Open Access

    ARTICLE

    Performance Evaluation of Nucleating Agents in Polypropylene Homopolymer

    RAVI KUMAR, VISHWA PRATAP SINGH, MADHUKAR PRAJAPATI, ASHWITH, PRIYANKA SINGH, SATYAJIT SAMANTA, SAIKAT BANERJEE*

    Journal of Polymer Materials, Vol.36, No.4, pp. 323-335, 2019, DOI:10.32381/JPM.2019.36.04.3

    Abstract Types of nucleating agents and their dosage level play an important role on the crystallinity of the polymer which controls the final properties like optical clarity, stiffness and reduced cycle time during molding. In this study, the efficiency of two different types of commercially available nucleating agents, phosphate ester and dicarboxylic acid based, have been studied. Both the nucleating agents were compounded with molding grade polypropylene homopolymer having melt flow index (MFI) of 12 g/10min at 2.16 Kg and 230°C, in a co-rotating twin screw extruder at two different dosage level, i.e. 300 ppm and… More >

  • Open Access

    ARTICLE

    Development and Characterization of Graphite Fluoride Dry Lubrication System by using Gamma Radiation

    SACHIN SINGHa, MUKTI TYAGIa,*, AJAY KUMAR TYAGIa, PRAVEEN KUMAR KAICKERa, LALIT VARSHNEYb

    Journal of Polymer Materials, Vol.36, No.4, pp. 305-321, 2019, DOI:10.32381/JPM.2019.36.04.2

    Abstract Graphite is the most suitable material as dry lubricant. However, its application as a lubricant is limited with necessity of moisture vapors. Alternatively, polytetrafluoroethylene (PTFE) has an excellent lubrication property but does not have mechanical characteristics. The effect of gamma radiation doses on the lubrication behavior of graphite –PTFE (Inoflon A-408) system has been studied using (TR-TW-30L) tribotester with thrust washer attachment. Different compositions of graphite and PTFE were prepared and irradiated by gamma rays. Improved tribological properties of graphite –PTFE system showed by decrease in coefficient of friction and wear. SEM-EDX, XRD and contact More >

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