Open Access
ARTICLE
Urethane Modified Hydrophobic Compact Wood Pulp Paper for Oil Spill Cleanup: A Preliminary Study
Gustavo de Souza, Ricardo K. Kramer, Antonio J. F. Carvalho*
Department of Materials Engineering, Sao Carlos School of Engineering (EESC), University of São Paulo (USP), São Paulo, Brazil
* Corresponding Author: Antonio J. F. Carvalho. Email:
(This article belongs to this Special Issue: 15th Brazilian Polymer Conference (15th CBPol))
Journal of Renewable Materials 2020, 8(10), 1257-1268. https://doi.org/10.32604/jrm.2020.011906
Received 04 June 2020; Accepted 31 July 2020; Issue published 31 August 2020
Abstract
Oil spills and oil/water wastewater are among the great concerns
regarding oil pollution. Existing technologies face many limitations and in some
cases are responsible for causing secondary pollution, therefore there is as seek for
environmental friendly solutions. Biomass, from which celluloses are highlighted,
are being employed for oil/water separation or oil absorbents membranes.
Usually, these membranes are obtained by freeze drying of CNF (cellulose nano-
fibrils) suspensions followed by chemical modification for hydrophobization,
which involves expensive process as chemical vapor deposition and expensive
reactants as sylanes, turning these processes hardly scalable. Here, we produced
a natural porous structure paper from eucalyptus pulp fibers modified by a dipping
and heating process in a blocked diisocyanate solution. After the surface treatment, contact angle with water reached 144° and water absorption reduced seven
times, keeping the good oil absorbance. The chemical modification process is
simple to be performed and use a very low quantity of reactant estimated to be
less than 0.1 wt% based on cellulose. The good mechanical properties of the
material allows its use in non usual conditions which can be of great importance
depending on the environmental conditions.
Keywords
Cite This Article
Souza, G. D., Kramer, R. K., J., A. (2020). Urethane Modified Hydrophobic Compact Wood Pulp Paper for Oil Spill Cleanup: A Preliminary Study.
Journal of Renewable Materials, 8(10), 1257–1268. https://doi.org/10.32604/jrm.2020.011906