Open Access

ARTICLE

Synthesis of Polyamides and Their Copolymers via Enzymatic Polymerization

by

Department of Polymer Chemistry, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands

* Corresponding Author:

Journal of Renewable Materials 2015, 3(4), 268-280. https://doi.org/10.7569/JRM.2015.634102

Received 17 January 2015; Accepted 15 March 2015;

Abstract

The selective and specific features of enzymes have drawn an enormous amount of attention for use as in-vitro catalysts in polymerization reactions. Various studies on the enzymatic synthesis of polyesters, polycarbonates, polysaccharides, polypeptides, and polyamides have been performed and some have been implemented on an industrial scale. Particularly in the synthesis of polyester and polyamides, lipases are the most used enzymes as catalysts for their polymerization. Polyamides are considered to be one of the largest engineering polymer families used in the automotive, electrical and electronics, and consumer goods industries; thus the enzymatic synthesis of polyamides will have a tremendous impact on environmental issues. Therefore, in this article, the enzyme-catalyzed synthesis of polyamides and their copolymers is reviewed with a focus on the type of polymerization the enzyme catalyzes and type of monomer used for the synthesis of polyamides.

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Keywords

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