Open Access

ARTICLE

Matrix-Assisted Laser Desorption-Ionization Time of Flight (MALDI-TOF) Mass Spectrometry of Phenol-FormaldehydeChestnut Tannin Resins

M.C. Lagel^1,*, A. Pizzi^1,2, S. Giovando³

1 LERMAB, University of Lorraine, 27 rue Philippe Séguin, 88026 Epinal, France
2 Dept. of Physics, King Abdulaziz University, Jeddah, Saudi Arabia
3 Silva Team, Silva Chimica, via Torre 7, 12080 San Michele Mondovi’, Italy

* Corresponding Author:

Journal of Renewable Materials 2014, 2(3), 207-219. https://doi.org/10.7569/JRM.2014.634111

Received 28 February 2014; Accepted 05 June 2014;

Abstract

Natural hydrolysable chestnut tannin extracts used to partially substitute phenol in Phenol-Formaldehyde (PF) resins for phenolic rigid foams were analysed by matrix-assisted desorption ionization time of fl ight (MALDI-TOF) mass spectrometry. PF only, chestnut only and PF-chestnut copolymerised oligomer types and distribution were determined. MALDI-TOF analyses of a PF control resin (with the same molar ratio) and of chestnut tannin extracts were performed in order to identify the peaks of molecular weights corresponding to copolymers of chestnut tannins with phenol and formaldehyde.

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Keywords

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