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Zoran S Petrovic´^*, Ivan Javni, Mihail Ionescu
Journal of Renewable Materials, Vol.1, No.3, pp. 167-186, 2013, DOI:10.7569/JRM.2013.634112
Abstract This paper reviews a part of the rich fi eld of oleochemicals, their synthesis and applications as precursors for polymers by referring to published data rather than discussing details of different reactions. The hope is to help readers in fi nding leads in the vast research area carried out over a long period of time, to avoid traps and to inspire new ideas for oil-based products and processes. More >

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Rodolfo J. González-Paz, Gerard Lligadas^*, Juan C. Ronda, Marina Galià, Virginia Cádiz
Journal of Renewable Materials, Vol.1, No.3, pp. 187-194, 2013, DOI:10.7569/JRM.2013.634114
Abstract A thiol-reactive linear polyurethane was synthesized from a vinyl-sulphide-containing diol and a commercial diisocyanate. The diol was obtained from 10-undecynol, an alkyne-derivatized fatty compound, using hydrothiolation as a key reaction step. 10-Undecynol was prepared by reduction of 10-undecinoic acid methyl ester, which was prepared by successive bromation, dehydrobromination of the corresponding alkenic fatty acid. Solution and surface polymer modifi cation with a fl uorescent thiol was successful. More >

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Yanxia Zhang¹, Tiina Nypelö^1,*, Carlos Salas¹, Julio Arboleda¹, Ingrid C. Hoeger^1,*, Orlando J. Rojas^1,2,*
Journal of Renewable Materials, Vol.1, No.3, pp. 195-211, 2013, DOI:10.7569/JRM.2013.634115
Abstract Cellulose nanofi brils (CNF), also known as nanofi brillar cellulose (NFC), are an advanced biomaterial made mainly from renewable forest and agricultural resources that have demonstrated exceptional performance in composites. In addition, they have been utilized in barrier coatings, food, transparent fl exible fi lms and other applications. Research on CNF has advanced rapidly over the last decade and several of the fundamental questions about production and characterization of CNF have been addressed. An interesting shift in focus in the recent reported literature indicates increased efforts aimed at taking advantage of the unique properties of More >

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Belén Begines, Francisca Zamora, M. Violante de Paz, Isaac Roffé, Manuel Mancera, Juan A. Galbis^*
Journal of Renewable Materials, Vol.1, No.3, pp. 212-221, 2013, DOI:10.7569/JRM.2013.634119
Abstract A batch of linear [m,n]-type sugar-based polyureas was synthesized by polyaddition reaction in solution from hexamethylene diisocyanate or 4,4’-methylene-bis(phenyl isocyanate) with the acyclic 2,3,4-tri-O-methyl-1,5- diamino-alditols having L-arabino, or xylo confi guration or the bicyclic 1,6-diamino-1,6-dideoxy-2,4:3,5-diO-methylene-D-glucitol. The polymers were obtained in good yields and fair molecular weights. All these polyureas were semicrystalline materials showing well-defi ned melting transition within the 86−171°C range, with T_g s being dependent on the aliphatic or aromatic nature of the diisocyanate used, and on the cyclic or acyclic chemical structure of the sugar moiety. They were found to be stable up to around More >

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Donglin Tang^1,2, Shanmugam Thiyagarajan^2,3, Bart A.J. Noordover^1,*, Cor E. Koning¹, Daan S. van Es³, Jacco van Haveren
Journal of Renewable Materials, Vol.1, No.3, pp. 222-230, 2013, DOI:10.7569/JRM.2013.634116
Abstract A series of fully renewable poly(ester urethane urea)s (PEUs) were synthesized from bio-based starting materials, e.g., the polyester diol, the diisocyanates including L-lysine diisocyanate (LDI) and isoidide diisocyanate (IIDI), the chain-extenders including 1,4-diaminobutane (bDA), diaminoisoidide (iDA) and di(aminobutyl) urea (b2 DA). It is found that the PEU based on the novel diisocyanate, IIDI, exhibits satisfactory thermal and mechanical properties. The LDI-based PEUs show less favorable thermal and mechanical properties than the IIDI-based counterpart, since the chemical structure of LDI is less regular than that of IIDI. However, by introducing a urea-containing dimeric diamine (b2 DA) More >

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