Open Access

ARTICLE

Feasibility Study of the Synthesis of Isocyanate-Free Polyurethanes from Catechin

Wissem Sahmim¹, Febrina Dellarose Boer¹, Hubert Chapuis¹, Firmin Obounou-Akong¹, Antonio Pizzi², Philippe Gérardin¹, Christine Gérardin-Charbonnier^1,*

1 Faculté des Sciences et Technologies, Laboratoire d’Etudes et de Recherche sur le Matériau Bois, EA 4370-USC INRAE, Université de Lorraine, Nancy, 54506, France
2 Laboratoire d’Etudes et de Recherche sur le Matériau Bois, EA 4370-USC INRAE, Université de Lorraine, Epinal, 88000, France

* Corresponding Author: Christine Gérardin-Charbonnier. Email:

(This article belongs to the Special Issue: Renewable Foam Materials and Composites)

Journal of Renewable Materials 2022, 10(5), 1175-1184. https://doi.org/10.32604/jrm.2022.016365

Received 01 March 2021; Accepted 26 July 2021; Issue published 22 December 2021

Abstract

With the current trend of increasing efforts to develop non-isocyanate-based polyurethanes (NIPUs), this study aimed to check the feasibility of the development of a method using cyclic carbonate modified catechin and amine to synthesis non-isocyanate urethane with the objective to further extend these results to polyurethane synthesis. The methods used in this study consist of four steps: glycidilation of catechin, hydrolysis of epoxide, cyclic carbonate synthesis, and carbamate synthesis through condensation of butylamine. The resulting products were analyzed using FTIR (Fourier transform infrared) spectroscopy and NMR (nuclear magnetic resonance) spectroscopy. The results showed that carbamate could be successfully obtained through this four-steps synthesis, opening the possibility to further developments for the synthesis of polyurethanes starting from catechin and condensed tannins.

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