Submission Deadline: 31 August 2024 (closed) View: 102
Recently, organic-inorganic composites have aroused considerable attention due to their tunable properties, where cellulose tailored semiconductors for artificial photocatalysis are typical examples. Although cellulose itself actually has no direct photocatalytic activity, it can facilitate semiconductor photocatalysts via two strategies: function as assistants and sacrifice as bio-templates. When utilized as assistants, its good hydrophilicity may accelerate the reaction in the water system, and it could also act as a scaffold to fix, disperse or even transform semiconductors through the interlinked ultrafine fibers and chemical interaction triggered by functional groups, which would remarkably promote their photocatalytic performances. Whereas some researchers just sacrifice cellulose as bio-templates by calcination or solvothermal treatment, the removal of cellulose could bring about delicate structures with high porosity and large surface area; alternatively, the inherited biochar skeleton would assist the photo-induced electron transfer. Beyond these, the reusability of photocatalysts is also of great importance for their practical applications. Benefiting from the fascinating features of low density, fibrillar morphology and strong mutual hydrogen bonds, cellulose could be easily manufactured into various monoliths with high mechanical ductility and flexibility, including films, gels (aerogel and hydrogel) and textiles, such heterogeneous and monolithic nature would endow photocatalysts with facile recycling features. Besides, the strong adhesion initiated by chemical interaction, especially hydrogen bonds, between cellulose and semiconductors guarantees the high stability of semiconductors. Thus, cellulose could remedy the defects of conventional semiconductors to a certain degree and further realize advanced photocatalysis, and it is worthy of studying the subject of cellulose tailored semiconductors.
This special issue of “Cellulose Tailored Semiconductors for Photocatalysis” will focus on the recent advances in the design and applications of cellulose-based photocatalysts. This special issue accepts research and review articles that will show a diversity of new developments in these areas:
(1) Construction of cellulose-based photocatalysts, including powder and monolith (films, gels (aerogel and hydrogel) and textiles) photocatalysts
(2) Application of cellulose-based photocatalysts