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ARTICLE

Synthesis and Characterization of Epoxy methacrylate of (2E, 6E)-Bis(4-hydroxybenzylidene)-4- methylcyclohexanone

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Department of Chemistry, Saurashtra University, Rajkot-360 005, Gujarat, India

* Corresponding Authors: e-mail:,

Journal of Polymer Materials 2019, 36(4), 391-399. https://doi.org/10.32381/JPM.2019.36.04.8

Abstract

The epoxymethcrylate resin (EMBHBCMA) of (2E, 6E)-bis(4-hydroxybenzylidene)-4- methylcyclohexanone(EMBHBC) was synthesized by condensing EMBHBC and methacrylic acid (1:2 mole ratio) by using 1,4-dioxane as a solvent and triethylamine as a catalyst at reflux temperature for 1-5 h to get acid value < 10. The structure of EMBHBCMA was supported by UV-Vis, FTIR, ¹ HNMR and ¹³CNMR spectroscopic techniques. Molecular weights and molecular weight distribution of EMBHBCMA were determined by gel permeation chromatography. EMBHBCMA is thermally stable up to about 300°C and followed two step degradation reactions. Kinetic parameters such as n, Ea, A and ΔS* were determined according to Anderson-Freeman method and discussed.

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Keywords

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