Open Access

ARTICLE

GENG SU, YA-JIE JIANG, HONG-BIN JU, YA-KUI WANG, TAO GENG^*
Journal of Polymer Materials, Vol.36, No.4, pp. 293-304, 2019, DOI:10.32381/JPM.2019.36.04.1
Abstract Two kinds of poly quaternary ammonium salts (PQAS) namely PDMC (poly (methacryloxyethyl trimethyl ammonium chloride)), CPAM (methacryloxyethyl trimethyl ammonium chloride / acrylamide copolymer) were prepared. The chemical structures of the PQAS were characterized by Fourier transform infrared (FT-IR), nuclear magnetic resonance (¹ H NMR) spectrum, thermogravimetric analysis (TGA), and scanning electron microscope (SEM). The antibacterial activity of PQAS against three kinds of bacteria and one kind of fungus, was evaluated by the method described in QB/T 2738-2012. Antibacterial tests showed that the antibacterial activity increased with the increase of cationicity and molecular weight on PQAS. It More >

View

217

Download

159

Open Access

ARTICLE

SACHIN SINGH^a, MUKTI TYAGI^a,*, AJAY KUMAR TYAGI^a, PRAVEEN KUMAR KAICKER^a, LALIT VARSHNEY^b
Journal of Polymer Materials, Vol.36, No.4, pp. 305-321, 2019, DOI:10.32381/JPM.2019.36.04.2
Abstract Graphite is the most suitable material as dry lubricant. However, its application as a lubricant is limited with necessity of moisture vapors. Alternatively, polytetrafluoroethylene (PTFE) has an excellent lubrication property but does not have mechanical characteristics. The effect of gamma radiation doses on the lubrication behavior of graphite –PTFE (Inoflon A-408) system has been studied using (TR-TW-30L) tribotester with thrust washer attachment. Different compositions of graphite and PTFE were prepared and irradiated by gamma rays. Improved tribological properties of graphite –PTFE system showed by decrease in coefficient of friction and wear. SEM-EDX, XRD and contact More >

View

176

Download

133

Open Access

ARTICLE

RAVI KUMAR, VISHWA PRATAP SINGH, MADHUKAR PRAJAPATI, ASHWITH, PRIYANKA SINGH, SATYAJIT SAMANTA, SAIKAT BANERJEE^*
Journal of Polymer Materials, Vol.36, No.4, pp. 323-335, 2019, DOI:10.32381/JPM.2019.36.04.3
Abstract Types of nucleating agents and their dosage level play an important role on the crystallinity of the polymer which controls the final properties like optical clarity, stiffness and reduced cycle time during molding. In this study, the efficiency of two different types of commercially available nucleating agents, phosphate ester and dicarboxylic acid based, have been studied. Both the nucleating agents were compounded with molding grade polypropylene homopolymer having melt flow index (MFI) of 12 g/10min at 2.16 Kg and 230°C, in a co-rotating twin screw extruder at two different dosage level, i.e. 300 ppm and… More >

View

190

Download

168

Open Access

ARTICLE

ÇAĞLA GÜL GÜLDİKEN, LEVENT AKYALÇIN, HASAN FERDİ GERÇEL^*
Journal of Polymer Materials, Vol.36, No.4, pp. 337-349, 2019, DOI:10.32381/JPM.2019.36.04.4
Abstract In the present study, polybenzimidazole (PBI) polymer which has a great importance in polymer electrolyte membrane (PEM) research was synthesized via the solution polycondensation method, under various synthesis conditions to put forward the effect of the synthesis parameters on the properties of the synthesized polymer and consequently to the quality of the prepared polymer electrolyte membrane. The synthesized polymers were characterized in terms of their chemical structure, thermal degradation behaviour, and molecular weight by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (¹ H NMR), thermogravimetric analysis (TGA). The Mechanical properties, acid-doping level capacity, proton More >

View

189

Download

152

Open Access

ARTICLE

B. MOULIPRASANTH^A, P. HARIHARAN^B
Journal of Polymer Materials, Vol.36, No.4, pp. 351-369, 2019, DOI:10.32381/JPM.2019.36.04.5
Abstract Electrical discharge machining is a non-traditional machining processes in which it is based upon thermal and electrical energy source as an interval energy pulse discharge in-between the work piece and tool electrode so as to remove the material. A systematical investigation of melting and vaporising of aluminium to find the output responses such as Material removal rate (MRR), Electrode wear rate (R_a), and Surface finish (EWR) in EDM using two different dielectrics was conducted as experimental work. The working fluids are Polyethylene glycol (PEG 600) and kerosene. It is the hour of need to get the More >

View

183

Download

140

Open Access

ARTICLE

DHARMESH B. SANKHAVARA, JALPA V. CHOPDA, JIGNESH P. PATEL, PARSOTAM H. PARSANIA^*
Journal of Polymer Materials, Vol.36, No.4, pp. 371-379, 2019, DOI:10.32381/JPM.2019.36.04.6
Abstract The epoxy methacrylate of (2E,6E)-2, 6-bis(4-hydroxybenzylidene)cyclohexanone (EBHBCMA) was synthesized by condensing 0.02 equi. EBHBC, 0.04 equi. methacrylic acid, 50 mL THF as a solvent and 0.2 mL triethylamine as a catalyst at reflux temperature for 1-5 h to get acid value < 10. EBHBCMA showed good solubility in common solvents. The structure of EBHBCMA was supported by UV-Vis., FTIR, 1 H NMR, and 13C NMR spectroscopic techniques. DSC thermogram of EBHBCMA exhibited two endothermic peaks (86.4 and 117.1 °C) and one exothermic peak (142.6°C) due to moisture release, melting and curing of the resin, respectively. More >

View

169

Download

148

Open Access

ARTICLE

JIANGBO WANG^*
Journal of Polymer Materials, Vol.36, No.4, pp. 381-389, 2019, DOI:10.32381/JPM.2019.36.04.7
Abstract In this study, a novel flame retardant polyvinylphenylsilsesquioxane (PVP) was added into epoxy resin (EP) to prepare EP/PVP (FREP) composites. The results of cone calorimeter measurement showed that in comparison with virgin EP, the peak heat release rate (PHRR) and total heat release (THR) of FREP were reduced by 27.3% and 10.4%, respectively. Moreover, the thermal degradation behavior of FREP was studied by the Kissinger and Ozawa-Flynn-Wall methods. The results suggested that the addition of PVP greatly enhanced the thermal stability of EP in the final stage, which could be attributed to that the branched More >

View

192

Download

162

Open Access

ARTICLE

JALPA V. CHOPDA, DHARMESH B. SANKHAVARA, JIGNESH P. PATEL, P. H. PARSANIA^*
Journal of Polymer Materials, Vol.36, No.4, pp. 391-399, 2019, DOI:10.32381/JPM.2019.36.04.8
Abstract The epoxymethcrylate resin (EMBHBCMA) of (2E, 6E)-bis(4-hydroxybenzylidene)-4- methylcyclohexanone(EMBHBC) was synthesized by condensing EMBHBC and methacrylic acid (1:2 mole ratio) by using 1,4-dioxane as a solvent and triethylamine as a catalyst at reflux temperature for 1-5 h to get acid value < 10. The structure of EMBHBCMA was supported by UV-Vis, FTIR, ¹ HNMR and ¹³CNMR spectroscopic techniques. Molecular weights and molecular weight distribution of EMBHBCMA were determined by gel permeation chromatography. EMBHBCMA is thermally stable up to about 300°C and followed two step degradation reactions. Kinetic parameters such as n, Ea, A and ΔS* were determined More >

View

189

Download

205