Open Access

ARTICLE

Microwave-Assisted Synthesis of Hydroxyl-Terminated Polybutadiene Based Polyurethanes with Superior Properties

NA TENG, JINYUE DAI^#, YONG WEN, JING CHEN^*, FEI LIU, JIN ZHU, HAINING NA^*

Cixi Institute of Biomedical Engineering, Ningbo Institute of Materials Technology and Engineering, Key Laboratory of Bio-based Polymeric Materials of Zhejiang Province, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, P.R. China

* Corresponding Authors: e-mail: (J. Chen); (H. N. NA)

Journal of Polymer Materials 2018, 35(1), 71-83.

Abstract

This study focuses on the microwave-assisted synthesis of hydroxyl-terminated polybutadiene (HTPB) based polyurethanes. Driven by microwave irradiation, the synthetic rate of HTPB based polyurethanes is three times faster than the synthesis operated by traditional oil-bath heating. Though the synthesis time is significantly decreased, polyurethanes synthesized with microwave irradiation exhibit comparable mechanical performances to the similar polyurethanes obtained by traditional oil-bath heating. The tensile strength and Young’s modulus of polyurethanes synthesized with microwave irradiation are also higher than conventional method. HTPB based polyurethanes also exhibit excellent thermal stability and hydrolysis resistance. Our research suggests a fast and interesting way to synthesize HTPB based polyurethanes.

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Keywords

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